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This document specifies a method for the determination of the boiling range distribution of petroleum products by capillary gas chromatography using flame ionization detection. The document is applicable to materials having a vapour pressure low enough to permit sampling at ambient temperature, and which have a boiling range of at least 100 °C. The document is applicable to materials with initial boiling points (IBP) above 100 °C and final boiling points (FBP) above 750 °C, for example, heavy distillate fuels and residuals. The method is not applicable to bituminous samples. The test method is not applicable for the analysis of petroleum or petroleum products containing low molecular weight components (for example naphthas, reformates, gasolines) or middle distillates like Diesel and Jet fuel. Petroleum or petroleum products containing blending components, which contain hetero atoms (for example alcohols, ethers, acids, or esters) or residue, are not to be analysed by this test method. NOTE For the purposes of this document, the terms “% (m/m)” and “% (V/V)” are used to represent respectively the mass fraction and the volume fraction. WARNING — The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.

This document specifies a method for the determination of the boiling range distribution of petroleum products by capillary gas chromatography using flame ionization detection. The document is applicable to materials having a vapour pressure low enough to permit sampling at ambient temperature and a boiling range of at least 100 °C. The document is applicable to distillates with initial boiling points (IBP) above 100 °C and final boiling points (FBP) below 750 °C, for example, middle distillates and lubricating base stocks. The test method is not applicable for the analysis of petroleum or petroleum products containing low molecular weight components (for example naphtha’s, reformates, gasolines) or middle distillates like Diesel and Jet fuel. Petroleum or petroleum products containing blending components which contain heteroatoms (for example alcohols, ethers, acids, or esters) or residue are not to be analysed by this test method. NOTE For the purposes of this document, the terms “% (m/m)” and “% (V/V)” are used to represent respectively the mass fraction and the volume fraction. WARNING — The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.

This document specifies a method for the determination of the boiling range distribution of petroleum products. The method is applicable to petroleum products and fractions with a final boiling point of 538 °C or lower at atmospheric pressure as determined by this document. This document does not apply to gasoline samples or gasoline components. The method is limited to products having a boiling range greater than 55 °C and having a vapour pressure sufficiently low to permit sampling at ambient temperature. The document describes two procedures. a) Procedure A allows a larger selection of columns and analysis conditions, such as packed and capillary columns as well as a thermal conductivity detector in addition to the flame ionization detector. Analysis times range from 14 min to 60 min. b) Procedure B is restricted to only three capillary columns and requires no sample dilution. The analysis time is reduced to about 8 min. Both procedures have been successfully applied to samples containing fatty acid methyl esters (FAME) up to 20 % (volume fraction). NOTE For the purposes of this document, the terms "% (mass fraction)" and "% (volume fraction)" are used to represent the mass fraction (µ), the volume fraction (φ) of a material.