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The method is based on decomposition of the test portion by fusion with sodium tetraborate and treatment with dilute nitric acid, addition of ammonium molybdate to convert silicate into a molybdatosilicate complex, reduction to molybdenum blue with ascorbic acid, and spectrophotometric measurement of the absorbance of the molybdenum blue complex at a wavelength of approximately 600 nm. Applies to silicon contents between 0,1 % and 5,0 % in natural iron ores, iron ore concentrates and agglomerates, including sinter products, especially for ores containing fluorine.

The method is applicable to phosphorus contents between 0,003 % (m/m) and 2 % (m/m) in natural iron ores, iron ore concentrates and agglomerates, including sinter products. The presence of arsenic, barium or titanium does not affect the result.

The method ist applicable to a concentration range of 0,005 to 1,0 % (m/m) of fluorine in natural iron ores, and iron ore concentrates and agglomerates including sinter products. Specifies principle, reagents, apparatus, sampling and samples, procedure, expression of results, and test report. ISO 4693 includes three annexes.