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This document specifies methods used to determine the concentration of plutonium and neptunium isotopes in water by inductively coupled plasma mass spectrometry (ICP-MS) (239Pu, 240Pu, 241Pu and 237Np). The concentrations obtained can be converted into activity concentrations of the different isotopes[9]. Due to its relatively short half-life and 238U isobaric interference, 238Pu can hardly be measured by this method. To quantify this isotope, other techniques can be used (ICP-MS with collision-reaction cell, ICP-MS/MS with collision-reaction cell or chemical separation). Alpha spectrometry measurement, as described in ISO 13167[10], is currently used[11]. This method is applicable to all types of water having a saline load less than 1 g·l−1. A dilution of the sample is possible to obtain a solution having a saline load and activity concentrations compatible with the preparation and the measurement assembly. A filtration at 0,45 μm is needed for determination of dissolved nuclides. Acidification and chemical separation of the sample are always needed. The limit of quantification depends on the chemical separation and the performance of the measurement device. This method covers the measurement of those isotopes in water in activity concentrations between around[12][13]: — 1 mBq·l−1 to 5 Bq·l−1 for 239Pu, 240Pu and 237Np; — 1 Bq·l−1 to 5 Bq·l−1 for 241Pu. In both cases, samples with higher activity concentrations than 5 Bq·l−1 can be measured if a dilution is performed before the chemical separation. It is possible to measure 241Pu following a pre-concentration step of at least 1 000.

This part of ISO 13164 gives general guidelines for sampling, packaging, and transporting of all kinds of water samples, for the measurement of the activity concentration of 222Rn.

The test methods fall into two categories:

a) direct measurement of the water sample without any transfer of phase (see ISO 13164-2[7]);

b) indirect measurement involving the transfer of the 222Rn from the aqueous phase to another phase (see ISO 13164-3[8] and 13164-4[9]).

The test methods can be applied either in the laboratory or on-site. The laboratory is responsible for ensuring the suitability of the test method for the water samples tested.

ISThis part of ISO 13164 specifies a test method for the determination of 222Rn activity concentration in a sample of water following its transfer from the aqueous phase to the gas phase by degassing and its detection. It gives recommendations for rapid measurements performed within less than 1 h. The 222Rn activity concentrations, which can be measured by this test method utilizing currently available instruments, range from 0,1 Bq∙l−1 to several hundred thousand becquerels per litre for a 100 ml test sample. This test method is used successfully with drinking water samples. The laboratory is responsible for ensuring the validity of this test method for water samples of untested matrices. This test method can be applied on field sites or in the laboratory.

This document applies to the testing of surfaces that may become contaminated by radioactive materials. The ease of decontamination is a property of a surface and an important criterion for selecting surface materials used in the nuclear industry, interim storage or disposal facilities from which contamination can be removed easily and rapidly without damaging the surface. The test described in this document is a rapid laboratory-based method to compare the ease of decontamination of different surface materials. The results from the test can be one parameter to take into account when selecting surface coatings such as varnish or impervious layers such as ceramics and other surfaces. The radionuclides used in this test are those commonly found in the nuclear industry (137Cs, 134Cs and 60Co) in aqueous form. The test can also be adopted for use with other radionuclides and other chemical forms, depending on the customer requirements, if the solutions are chemically stable and do not corrode the test specimen. The test does not measure the ease of decontamination of the surface materials in practical use, as this depends on the radionuclide(s) present, their chemical form, the duration of exposure to the contaminant and the environmental conditions amongst other factors. The test method is not intended to describe general decontamination procedures or to assess the efficiency of decontamination procedures (see ISO 7503-1 to ISO 7503-3). The test method is not suitable for use of radiochemicals if the radionuclide emits low energy gamma rays or beta particles that are readily attenuated in the surface.