Vattenkvalitet

Kommittébeteckning: SIS/TK 424 (Kemiska vattenundersökningar)
Källa: CEN
Svarsdatum: den 7 nov 2022
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This document specifies a method for the determination of the dissolved fraction of selected perfluoroalkyl and polyfluoroalkyl substances (PFAS) in non-filtrated drinking water containing less than 0,5 g/l solid particulate material (SPM) using liquid chromatography-tandem mass spectrometry (LC-MS/MS). The applicability of the method to further types of water like fresh waters (e.g. ground water, surface water) or e.g. treated waste water is be validated separately for each individual case.
For each target compound both, eventually occurring branched isomers and the respective non-branched isomer, are quantified together. The selected set of substances determined by this method is representative for a wide variety of PFAS. The analytes specified in Table 1 have been validated and can be determined by this method. The list given in this table can be modified depending on the purpose and focus of the method. The lower application range of this method can vary depending on the sensitivity of the equipment used and the matrix of the samples. For many substances to which this document applies a limit of quantification (LOQ) of 1 ng/l can be achieved. Using high volume direct injection as described in part A or SPE as described in part B of the method allows lower LOQs. Analytical limitations can occur with short-chain PFAS or PFAS with more than ten carbon atoms in the carbon chain. Actual LOQs can depend on the blank values realized by individual laboratories as well.
NOTE This document enables the analysis of those 20 PFAS which are listed in point 3 of Part B of Annex III of the EU Drinking Water Directive, EU 2020/2184, for the surveillance of the parametric limit value of 0,10 μg/l for the sum of PFAS.
Furthermore, alternatives and substitutes for these PFAS substances can be analysed using this document as well.

Kommittébeteckning: SIS/TK 424 (Kemiska vattenundersökningar)
Källa: CEN
Svarsdatum: den 27 nov 2022
Se merSe mindre
 

This document sets out the general principles for, and provides guidance on, the design of sampling programmes and sampling techniques for all aspects of sampling of water (including waste waters, sludges, effluents, suspended solids and sediments).
This document does not include detailed instructions for specific sampling situations, which are covered in various other parts of ISO 5667 and in ISO 19458.